Servo Motor¶
This example is based on the first servo I grabbed from my shelf
Note
TowerPro MG90S Micro servo (TowerPro site)
Accuracy¶
Default external measurements will be to specification (so you may use it in your own creations without issue).
Default internal measurements, and design will be estimated based on external observation; I’m not looking to infringe copyright.
What I design might actually work if you printed it, but that’s not the point of this exercise
Hierarchy¶
The servo’s Assembly
contains the following Assembly
and
Part
instances:
servo
├── enclosure
│ ├─○ shell
│ ├─○ end_cap
│ └── fasteners
│ ├── front_left
│ │ ├─○ bolt
│ │ ├─○ washer (?)
│ │ └─○ nut
│ ├── front_right
│ │ ...
│ ├── back_left
│ │ ...
│ └── back_right
│ ...
├── gearbox
│ ├── bearing
│ │ ├─○ outer_ring
│ │ ├── rolling_elements
│ │ │ ├─○ ball_1
│ │ │ │ ...
│ │ │ └─○ ball_n
│ │ ├─○ retainer
│ │ └─○ inner_ring
│ ├─○ main_shaft
│ ├─○ middle_shaft
│ └─○ drive_shaft
├── motor
│ ├── base_bearing ...
│ ├── drive_bearing ...
│ ├── rotor
│ │ └○ shaft
│ └─○ stator
└─ driver
├── board
│ ├─○ pcb
│ ├── ... (components)
│ └─○ potentiometer
└─○ connector
Where:
─
denotes anAssembly
, and○
denotes aPart
The idea being that following branches should always end in a Part
(so the ○
is a leaf)
Display¶
Todo
display completed servo example
from cqparts import display
# TODO: import Servo
servo = Servo() # use default values
display(
servo,
highlight=[
servo.find('gearbox.bearing'), # assembly (branch)
servo.find('motor.rotor.shaft'), # part (leaf)
],
)


Public Member Functions | |
| go_result | init (go_motion_spec *space, go_integer size, go_real deltat) |
| go_result | reset () |
| Reset motion queue. Null motion type, reset start and set end to start, Zero number of motions on queue, last_id of motion on queue, time. Init timescale to 1.0. More... | |
| go_result | set_type (go_flag type) |
| Set type of motion queueing done: GO_MOTION_NONE, GO_MOTION_JOINT, GO_MOTION_UJOINT, GO_MOTION_WORLD. More... | |
| go_flag | get_type () |
| go_result | set_joint_number (go_integer joints) |
| Set number of joints. Must positive andless than GO_MOTION_JOINT_NUM. More... | |
| go_integer | get_joint_number () |
| Get number of joints. More... | |
| go_result | set_here (const go_position *here) |
| Set current position - either joint values or world Cartesian pose. More... | |
| go_result | set_cycle_time (go_real deltat) |
| Set deltat, the time in seconds per cycle. More... | |
| go_result | set_scale (go_real scale, go_real scale_v, go_real scale_a) |
| go_result | append (const go_motion_spec *motion) |
| Append motion_spec onto queue. if type is GO_MOTION_JOINT then motion is done as append_joint if type is GO_MOTION_UJOINT then motion is done as append_ujoint if type is GO_MOTION_WORLD then motion is done as append_world. More... | |
| go_result | number (go_integer *number) |
| go_result | size (go_integer *size) |
| go_result | head (go_motion_spec *motion) |
| Get the head of the motion queue. More... | |
| go_result | here (go_position *position) |
| Get the here position and store into pointer to go_motion_spec. More... | |
| go_result | there (go_position *position) |
| Get the there position and store into the motion pointer to go_motion_spec. More... | |
| go_result | interp (go_position *position) |
| Do interpret cycle and store result into position pointer. Only if there's something on the queue do we want to increment the queue time. It was set to 0 when the queue was emptied, and will not be set to zero when the next move is appended. More... | |
| go_result | stop (go_motion_queue *queue) |
| go_result | set_id (go_integer id) |
| Set id of last motion appended. More... | |
| go_integer | last_id () |
| Get id of last motion appended. More... | |
| go_flag | is_empty () |
| go_result | erase () |
| go_result | drop_pending () |
| go_result | stop () |
| Stop queue interpret cycle now. Don't need to stop an empty or stopping queue store computed joint/world motion. point our attention at the current motion. Call go_traj_cj_stop for each joint- or tran/rot motion, so that each stops as fast as it can. The longest to stop will set the revised stop time, and each will be extended to stop at that longest time. Note that the specptr values are incremental for the move, as the original distance passed to go_traj_cj_compute was the incremental distance. More... | |
Protected Member Functions | |
| go_result | append_joint (const go_motion_spec *motion) |
| go_result | append_ujoint (const go_motion_spec *motion) |
| go_result | append_world (const go_motion_spec *motion) |
| go_result | interp_joint (go_real *joint) |
| go_result | interp_world (go_pose *pose) |
| go_result | interp_world (go_motion_spec *motion, go_real time, go_pose *pose) |
Protected Attributes | |
| go_flag | _type |
| go_position | _here |
| go_position | _there |
| go_motion_spec * | _startptr |
| go_motion_spec * | _endptr |
| go_motion_spec * | _start |
| go_motion_spec * | _end |
| go_integer | _size |
| go_integer | _joint_num |
| go_integer | _number |
| go_integer | _last_id |
| go_real | _deltat |
| go_real | _time |
| go_scale_spec | _timescale |
| go_result gomotion::go_motion_queue::append | ( | const go_motion_spec * | motion | ) |
Append motion_spec onto queue. if type is GO_MOTION_JOINT then motion is done as append_joint if type is GO_MOTION_UJOINT then motion is done as append_ujoint if type is GO_MOTION_WORLD then motion is done as append_world.
| motion | is a pointer to a motion spec. |
| go_integer gomotion::go_motion_queue::get_joint_number | ( | ) |
Get number of joints.
| go_result gomotion::go_motion_queue::head | ( | go_motion_spec * | motion | ) |
Get the head of the motion queue.
| motion | is a pointer to store the head of the motion queue. |
| go_result gomotion::go_motion_queue::here | ( | go_position * | position | ) |
Get the here position and store into pointer to go_motion_spec.
| position | is a pointer to store here motion spec. |
| go_result gomotion::go_motion_queue::interp | ( | go_position * | position | ) |
Do interpret cycle and store result into position pointer. Only if there's something on the queue do we want to increment the queue time. It was set to 0 when the queue was emptied, and will not be set to zero when the next move is appended.
| position | is a pointer to store computed joint/world motion. |
| go_integer gomotion::go_motion_queue::last_id | ( | ) |
Get id of last motion appended.
| go_result gomotion::go_motion_queue::reset | ( | ) |
Reset motion queue. Null motion type, reset start and set end to start, Zero number of motions on queue, last_id of motion on queue, time. Init timescale to 1.0.
| go_result gomotion::go_motion_queue::set_cycle_time | ( | go_real | deltat | ) |
Set deltat, the time in seconds per cycle.
| deltat | is time in real seconds, so fractional seconds possible. |
| go_result gomotion::go_motion_queue::set_here | ( | const go_position * | here | ) |
Set current position - either joint values or world Cartesian pose.
| here | as a pointer to a go_position |
| go_result gomotion::go_motion_queue::set_id | ( | go_integer | id | ) |
Set id of last motion appended.
| integer | value for last id of motion queued. FIXME: why would it ever not be incremental? |
| go_result gomotion::go_motion_queue::set_joint_number | ( | go_integer | joints | ) |
Set number of joints. Must positive andless than GO_MOTION_JOINT_NUM.
| joints | number of joints |
| go_result gomotion::go_motion_queue::set_type | ( | go_flag | type | ) |
Set type of motion queueing done: GO_MOTION_NONE, GO_MOTION_JOINT, GO_MOTION_UJOINT, GO_MOTION_WORLD.
these flags are used to further specify types of world motion: GO_MOTION_LINEAR, GO_MOTION_CIRCULAR
| go_result gomotion::go_motion_queue::stop | ( | ) |
Stop queue interpret cycle now. Don't need to stop an empty or stopping queue store computed joint/world motion. point our attention at the current motion. Call go_traj_cj_stop for each joint- or tran/rot motion, so that each stops as fast as it can. The longest to stop will set the revised stop time, and each will be extended to stop at that longest time. Note that the specptr values are incremental for the move, as the original distance passed to go_traj_cj_compute was the incremental distance.
| go_result gomotion::go_motion_queue::there | ( | go_position * | position | ) |
Get the there position and store into the motion pointer to go_motion_spec.
| position | is a pointer to store there motion spec. |
|
protected |
cycle time
|
protected |
ptr to last (empty) entry
|
protected |
the original end
|
protected |
initial starting point
|
protected |
number of joints to be interpolated
|
protected |
id of last motion appended
|
protected |
number of motions on queue
|
protected |
size of whole queue
|
protected |
ptr to first entry of the queue
|
protected |
ptr to original start
|
protected |
where the end is
|
protected |
time into the current spec
|
protected |
walked-in time scale factor
|
protected |
go_MOTION_JOINT for joint, otherwise world


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FITSIO Home
Next: 9.3 Specialized Header Keyword
Up: 9. Specialized CFITSIO Interface
Previous: 9.1 FITS File Access
Contents
- 1
- Get the byte offsets in the FITS file to the start of the header
and the start and end of the data in the CHDU. The difference
between headstart and dataend equals the size of the CHDU. If the
CHDU is the last HDU in the file, then dataend is also equal to the
size of the entire FITS file. Null pointers may be input for any
of the address parameters if their values are not needed.
int fits_get_hduaddr / ffghad (only supports files up to 2.1 GB in size)
(fitsfile *fptr, > long *headstart, long *datastart, long *dataend,
int *status)
int fits_get_hduaddrll / ffghadll (supports large files)
(fitsfile *fptr, > LONGLONG *headstart, LONGLONG *datastart,
LONGLONG *dataend, int *status)
- 2
- Create (append) a new empty HDU at the end of the FITS file.
This is now the CHDU but it is completely empty and has
no header keywords. It is recommended that fits_create_img or
fits_create_tbl be used instead of this routine.
int fits_create_hdu / ffcrhd
(fitsfile *fptr, > int *status)
- 3
- Insert a new IMAGE extension immediately following the CHDU, or
insert a new Primary Array at the beginning of the file. Any
following extensions in the file will be shifted down to make room
for the new extension. If the CHDU is the last HDU in the file
then the new image extension will simply be appended to the end of
the file. One can force a new primary array to be inserted at the
beginning of the FITS file by setting status = PREPEND_PRIMARY prior
to calling the routine. In this case the old primary array will be
converted to an IMAGE extension. The new extension (or primary
array) will become the CHDU. Refer to Chapter 9 for a list of
pre-defined bitpix values.
int fits_insert_img / ffiimg
(fitsfile *fptr, int bitpix, int naxis, long *naxes, > int *status)
int fits_insert_imgll / ffiimgll
(fitsfile *fptr, int bitpix, int naxis, LONGLONG *naxes, > int *status)
- 4
- Insert a new ASCII or binary table extension immediately following the CHDU.
Any following extensions will be shifted down to make room for the
new extension. If there are no other following extensions then the
new table extension will simply be appended to the end of the
file. If the FITS file is currently empty then this routine will
create a dummy primary array before appending the table to it. The
new extension will become the CHDU. The tunit and extname
parameters are optional and a null pointer may be given if they are
not defined. When inserting an ASCII table with
fits_insert_atbl, a null pointer may given for the *tbcol
parameter in which case each column of the table will be separated
by a single space character. Similarly, if the input value of
rowlen is 0, then CFITSIO will calculate the default rowlength
based on the tbcol and ttype values. Under normal circumstances,
the nrows
paramenter should have a value of 0; CFITSIO will automatically update
the number of rows as data is written to the table. When inserting a binary table
with fits_insert_btbl, if there are following extensions in the
file and if the table contains variable length array columns then
pcount must specify the expected final size of the data heap,
otherwise pcount must = 0.
int fits_insert_atbl / ffitab
(fitsfile *fptr, LONGLONG rowlen, LONGLONG nrows, int tfields, char *ttype[],
long *tbcol, char *tform[], char *tunit[], char *extname, > int *status)
int fits_insert_btbl / ffibin
(fitsfile *fptr, LONGLONG nrows, int tfields, char **ttype,
char **tform, char **tunit, char *extname, long pcount, > int *status)
- 5
- Modify the size, dimensions, and/or data type of the current
primary array or image extension. If the new image, as specified
by the input arguments, is larger than the current existing image
in the FITS file then zero fill data will be inserted at the end
of the current image and any following extensions will be moved
further back in the file. Similarly, if the new image is
smaller than the current image then any following extensions
will be shifted up towards the beginning of the FITS file
and the image data will be truncated to the new size.
This routine rewrites the BITPIX, NAXIS, and NAXISn keywords
with the appropriate values for the new image.
int fits_resize_img / ffrsim
(fitsfile *fptr, int bitpix, int naxis, long *naxes, > int *status)
int fits_resize_imgll / ffrsimll
(fitsfile *fptr, int bitpix, int naxis, LONGLONG *naxes, > int *status)
- 6
- Copy the data (and not the header) from the CHDU associated with infptr
to the CHDU associated with outfptr. This will overwrite any data
previously in the output CHDU. This low level routine is used by
fits_copy_hdu, but it may also be useful in certain application programs
that want to copy the data from one FITS file to another but also
want to modify the header keywords. The required FITS header keywords
which define the structure of the HDU must be written to the
output CHDU before calling this routine.
int fits_copy_data / ffcpdt
(fitsfile *infptr, fitsfile *outfptr, > int *status)
- 7
- Read or write a specified number of bytes starting at the specified byte
offset from the start of the extension data unit. These low
level routine are intended mainly for accessing the data in
non-standard, conforming extensions, and should not be used for standard
IMAGE, TABLE, or BINTABLE extensions.
int fits_read_ext / ffgextn
(fitsfile *fptr, LONGLONG offset, LONGLONG nbytes, void *buffer)
int fits_write_ext / ffpextn
(fitsfile *fptr, LONGLONG offset, LONGLONG nbytes, void *buffer)
- 8
- This routine forces CFITSIO to rescan the current header keywords that
define the structure of the HDU (such as the NAXIS and BITPIX
keywords) so that it reinitializes the internal buffers that
describe the HDU structure. This routine is useful for
reinitializing the structure of an HDU if any of the required
keywords (e.g., NAXISn) have been modified. In practice it should
rarely be necessary to call this routine because CFITSIO
internally calls it in most situations.
int fits_set_hdustruc / ffrdef
(fitsfile *fptr, > int *status) (DEPRECATED)
FITSIO Home
Next: 9.3 Specialized Header Keyword
Up: 9. Specialized CFITSIO Interface
Previous: 9.1 FITS File Access
Contents


Functions for testing if the covariance structure of 2-dimensional data (e.g. samples of surfaces X_i = X_i(s,t)) is separable, i.e. if covariance(X) = C_1 x C_2. A complete descriptions of the implemented tests can be found in the paper Aston, John A. D.; Pigoli, Davide; Tavakoli, Shahin. Tests for separability in nonparametric covariance operators of random surfaces. Ann. Statist. 45 (2017), no. 4, 1431–1461. <doi:10.1214/16-AOS1495> <https://projecteuclid.org/euclid.aos/1498636862> <arXiv:1505.02023>.
| Version: | 1.1.0 |
| Depends: | R (≥ 3.2.3) |
| Imports: | mvtnorm (≥ 1.0.4) |
| Published: | 2018-05-06 |
| Author: | Shahin Tavakoli [aut, cre], Davide Pigoli [ctb], John Aston [ctb] |
| Maintainer: | Shahin Tavakoli <s.tavakoli at warwick.ac.uk> |
| License: | GPL-2 |
| URL: | http://arxiv.org/abs/1505.02023 |
| NeedsCompilation: | no |
| In views: | FunctionalData |
| CRAN checks: | covsep results |
| Reference manual: | covsep.pdf |
| Package source: | covsep_1.1.0.tar.gz |
| Windows binaries: | r-devel: covsep_1.1.0.zip, r-release: covsep_1.1.0.zip, r-oldrel: covsep_1.1.0.zip |
| OS X binaries: | r-release: covsep_1.1.0.tgz, r-oldrel: covsep_1.1.0.tgz |
| Old sources: | covsep archive |
Please use the canonical form https://CRAN.R-project.org/package=covsep to link to this page.


Chapter 2 Workshop Answers for Week 2
2.1 Short mathematical question - Quantum Yield and lifetime
The quantum yield and lifetime of a dye were measured to be 0.43 & 2.6 ns respectively. What is the natural lifetime?
The fluorescence quantum yield (equation (2.2) and fluorescence lifetime (equation (2.2)) are related to the rate constants for the different decay processes.
\[\begin{equation} \phi_f = \frac{k_f^0}{k_f^0+k_{ic}+ k_{ST}+k_{\textrm{other}}} \tag{2.1} \end{equation}\]
\[\begin{equation} \tau_f = \frac{1}{k_f^0+k_{ic}+ k_{ST}+k_{\textrm{other}}} \tag{2.2} \end{equation}\]
The natural lifetime is the lifetime when the only decay pathway is fluorescence emission (equation (2.3)).
\[\begin{equation} \tau_f^0 = \frac{1}{k_f^0} \tag{2.3} \end{equation}\]
Combining equations (2.1) and (2.2):
\[\begin{equation*} \frac{\tau_f}{\phi_f}=\frac{\frac{1}{k_f^0+k_{ic}+ k_{ST}+k_{\textrm{other}}}}{\frac{k_f^0}{k_f^0+k_{ic}+ k_{ST}+k_{\textrm{other}}}}=\frac{1}{k_f^0}=\tau_f^0 \end{equation*}\]
Consequently \(\tau_f^0 = \frac{\tau_f}{\phi_f}=\frac{2.6}{0.43}= 6.0\) ns
2.2 Short conceptual question - Effect of other processes
For a given value of τ0 what happens to the lifetime and quantum yield as kIC and kISC increases?
If \(k_f^0\) is fixed (which it is for a given chromophore) then as we adjust the other rate constants in equation (2.2) the emission lifetime (the time it takes for the intensity to reduce to 1/e of the initial intensity) decreases, as shown in figure 2.1.
2.3 Conceptual question - Effect of structure
Fluorescein (figure 2.2) in basic aqueous solution has a quantum yield of fluorescence, Φf, of 0.95, and fluorescence lifetime, τf, of 4.1 ns.
Suggest why the fluorescence quantum yield in this system is so high.
The only things that affect the quantum yield and lifetime (equations (2.2) and (2.2)) are the different rate constants involved. The quantum yield is a measure of the proportion of excited states which decay by each pathway.
Therefore if the quantum yield of fluorescence is near unity then neither the rate of intersystem crossing or internal conversion is large. Intersystem crossing may occur due to the change in orbital type offered, but given the lack of heavy atoms this rate is unlikely to be high and will probably be a negligable proprortion given the high rates of other processes.
The rate of intersystem crossing is more efficient for rotations than vibrations (due to the closwer spacing of rotational energy levels), therefore if rotations can occur the rate of internal conversion tends to be quite high. In this case there is only one likely bond that could rotate to loose the excited state of the system. This is the single bond linking the two ring systems. Rotation around this bond is severly inhibited though due to the presence of the acid group which restricts rotation.
Please note that it is rotations around bonds that cross the conjugation within the molecule that allow for the most efficient energy loss.
2.4 Conceptual question - lack of symmetry in spectra.
The absorption and emission spectrum of fluorescein is shown in figure (2.3).
Why are the absorption bands between 200 – 350 nm not reflected in the emission spectrum?
Kasha’s rule states "An excited state always emits from the lowest energy level of that spin multiplicity state. Consequently we can excite into any available orbital, but the excited state will rapidly decay into the lowest energy level of that multiplicity. So although we are exciting from S0 into S1, S2, S3… any excited state will rapidly decay by internal conversion down to the S1 excited state and all emission will occur from this state.
Kasha’s rule is a consequence of the energy gap law which I alluded to when talking about the special case of azulene, but this will be covered in a video specifically talking about the energy gap law.
2.5 Conceptual question - Stokes’ shift
The inorganic dye [Ru(bpy)3]2+ has a measured lifetime in water of 580 ns and a natural lifetime of 13.8 µs. The spectrum is shown in figure 2.4. What is the origin of the large Stokes’ shift in this system?
Firstly we need to separate two things - the first is just the origin of the Stokes’ shift due to the transition of an electron occuring very quickly leaving an optimised state to occupy an unoptimised state, which later relaxes. A typical Stokes’ shift is ~20 nm, the Stokes’ shift in this example is more than 150 nm… why?
If we consider the system that we have at hand, in this case [Ru(bpy)3]2+ we can note the HOMO-LUMO transition is an MLCT. This has a large difference in structure of the HOMO & LUMO with a redistribution of charge which will also have a large effect on the arrangement of the solvent shell. Given this large difference in optimised structure there would be a large shift.
However this isn’t the only factor, the natural lifetime of 13.8 µs would indicate that the emission transition is phosphorescence, this spin forbidden transition has electrons alligned in parallel which is lower than the corresponding singlet state. So after excitation there is a change in multiplicity of the excited state, this lowers the energy of the system further moving the \(\lambda _{max}\) of emission to lower energy (longer wavelength).
Data from Shi et al., Synthesis and characterization of phosphorescent two coordinate copper(I) complexes bearing diamidocarbene ligands. Dalton Trans., 2017,46, 745-752.
2.6 Conceptual question - the effect of binding on emission
The asymmetric cyanine dye YO-Pro-1 is a DNA stain because it has a large increase on fluorescence emission when binding to DNA. The lifetime in free solution is around 2 ps and when bound to DNA is 2.4 ns. What is the structural origin of the large increase of emission upon binding?
The chromophore YO-Pro-1 has a methine bridge between the two halves of the chromophore, this offers efficient loss of the excited state via internal conversion (see question 2.3. As noted earlier free rotation around a bond which cuts across the conjugation is particularly efficient in deactivating an excited state.
If this pathway is inhibited by binding to the DNA (the dye intercalates between the base pairs but any dye DNA interaction would inhibit this mechanism of excited state decay) then the fluorescence lifetime will increase (equation (2.2)).
2.7 Extended question - Properties of Ethidium Bromide (Example Exam Question)
Ethidium bromide (EB, figure 2.7 is used as a DNA stain, which is essentially non-fluorescent in aqueous solution, but shows a strong enhancement of emission upon binding to double stranded DNA (which has a negatively charged backbone).
Emission is almost exclusively from the singlet excited state, but a triplet state has been shown to exist, which emits with a low quantum yield (ΦP = 0.00006).
- Sketch a Jablonski diagram for the processes you know to occur.
If phosphorescecne occurs there must be some intersystem crossing in both directions.
- The molar extinction coefficient, ε, of EB has be measured to be 78500 M−1 cm−1. What factors contribute to EB having such a high extinction coefficient?
There is a rigid structure indicating a similar ground and excited state strucutre, which would lead to a good overlap integrals between the HOMO and LUMO. THe molar extinction coefficient is a measure of this overlap integral.
The following spectra, lifetimes and quantum yield have been measured for EB in different free solution and DNA systems:
Table: (#tab:ethidiumlifetime) The lifetimes and quantum yields of ethidium bromide in aquous solution and when bound to DNA in protiated and deuterated systems.
| τ / ns | Φf | |
|---|---|---|
| H2O (no DNA) | 1.6 | 0.012 |
| D2O (no DNA) | 6.3 | |
| DNA | 28.3 | 0.220 |
| DNA (deuterated) | 38.4 |
- What factors likely lead to an enhancement of fluorescence quantum yield upon binding to DNA?
The chromophore single bond between the two halves of the chromophore, this offers efficient loss of the excited state via internal conversion (see question 2.3. As noted earlier free rotation around a bond which cuts across the conjugation is particularly efficient in deactivating an excited state.
If this pathway is inhibited by binding to the DNA (the dye intercalates between the base pairs but any dye DNA interaction would inhibit this mechanism of excited state decay) then the fluorescence lifetime will increase (equation (2.2)).
- Show that the natural lifetime of EB is 129 ns.
\[\begin{equation*} \phi_f = \frac{k_f^0}{k_f^0+k_{ic}+ k_{ST}+k_{\textrm{other}}} \end{equation*}\]
\[\begin{equation*} \tau_f = \frac{1}{k_f^0+k_{ic}+ k_{ST}+k_{\textrm{other}}} \end{equation*}\]
The natural lifetime is the lifetime when the only decay pathway is fluorescence emission (equation (2.3)).
\[\begin{equation*} \tau_f^0 = \frac{1}{k_f^0} \end{equation*}\]
Combining equations (2.2) and (2.2):
\[\begin{equation*} \frac{\tau_f}{\phi_f}=\frac{\frac{1}{k_f^0+k_{ic}+ k_{ST}+k_{\textrm{other}}}}{\frac{k_f^0}{k_f^0+k_{ic}+ k_{ST}+k_{\textrm{other}}}}=\frac{1}{k_f^0}=\tau_f^0 \end{equation*}\]
Consequently \(\tau_f^0 = \frac{\tau_f}{\phi_f}=\frac{1.6}{0.012}= 129\) ns
- What is the origin of the large Stoke’s shift (λ~max ex~ = 520 nm, λ~max em~ = 608 nm)
We are told the transition is fluorescence, but it has a very long natural lifetime. This long lifetime would indicate that despite the transition being selection rule allowed there is a structural explanation for the inefficiency of this process.
This would indicate that there is now a poor overlap integral indcating a poor overlap of the excited state and ground state structures, or there is a large difference in the structures of the excited and ground states.
This large difference in structure would be accounted for in the Stokes’ shift - a large deviation in structure would lead to a larger energy loss upon the optimisation of the excited state.
- What transitions are responsible for the absorption features in the: 400-600 nm range 200-350 nm range
The molecule has hetero atoms and so there will be both \(n-\pi*\) and \(\pi-\pi*\) transitions, the \(n-\pi*\) transitions will occur at lower energy (higher wavelength) and be the HOMO-LUMO transition.
- Why are the features in the 200-350 nm range not replicated in the emission spectrum?
Kasha’s rule states "An excited state always emits from the lowest energy level of that spin multiplicity state. Consequently we can excite into any available orbital, but the excited state will rapidly decay into the lowest energy level of that multiplicity. So although we are exciting from S0 into S1, S2, S3… any excited state will rapidly decay by internal conversion down to the S1 excited state and all emission will occur from this state.
- Why does deuterating the solvent (or DNA) effect the lifetime of the excited state?
Ultimately because it affects the rates of internal conversion, and so the lifetime is changed as described in equation @(eq:lifetimefluor). We will learn more as to why when we cover the energy gap law.
- What effect would freezing the samples have on the lifetime, fluorescence quantum yield & phosphorescence quantum yield.
You would expect the emission lifetime and quantum yield to increase on freezing (as described in equation @(eq:lifetimefluor)) as the efficiency (and therefore rate) of internal conversion mechanisms (particularly rotational relaxation) would be dramatically reduced in solid systems.
A study of the thermodynamics of the dye DNA system measured the binding constant of EB with DNA to be 1.05 × 106.
- Why is the measured quantum yield for a system containing 2 µM EB and 20 mM DNA only 0.18?
This will be due to there being two states - one where the chromophore is bound, one where it is not. It is an equilibrium so not all dye will be bound to DNA. When not bound there is no fluorescence enhancement. The quantum yield we see is in fact a weighted average between the two states.
This is a problem solving question and any reasonable attempt would have been given credit. It is demonstrating an ability to think about data and the problem in a scientific manner.
- Why would increasing the ionic strength of the solution, increase the fluorescence intensity of EB in solution with DNA?
This would push the equilibrium to form the dye:DNA complex increasing binding, as the binding increases the proportion of molecules displaying the higher quantum yield increases and the overall emission intensity of the sample increases.
This is a problem solving question and any reasonable attempt would have been given credit. It is demonstrating an ability to think about data and the problem in a scientific manner.


---
layout: post
title: "My Week in Review"
date: 2016-01-03 18:35:00 +0000
tags:
image: https://s3.amazonaws.com/hackedu/2016-1-1-fireworks.jpg
imagecredits: https://www.flickr.com/photos/jeffanddayna/2637637797
---
Travel
Hack Education
Writing Elsewhere
Speaking
Other Projects
- I continued to make updates across my websites
- Therapy
- I’m now officially a “visiting scholar” at UW Madison, although I haven’t managed to get access to the library yet
- I added “Danny Bonaduce” to Wikipedia’s list of famous red-heads
- I updated my CV
- I updated my passwords
Reading and Viewing
- I read Neil Selwyn’s new book, Is Technology Good for Education?
- I watched the new Sherlock episode, The Abominable Bride
- I’ve watched a fair number of bowl games
Family and Friends
- Kin’s daughter was here with us through New Year’s Eve.
- For the first time since I can remember, Kin and I went out for New Year’s. At the party: Abbie Wambach.


07.10.201930.11.201901.12.201915.12.2019
31.12.201901.01.202030.01.2020
30.03.202030.04.2020
15.05.202016.05.202001.06.2020
Programme
- Draft concept
- key-note speakers and lecturers contacted
Orga/Admission
- Call for applications
- First acceptance notifiation to applicants
- First deadline for acceptance
- Second acceptance notifiation to applicants
- Second deadline for acceptance
- Admission procedure
Advertising
- Website for programme, CfA, admission procedure
- Posted advertisement(Posters,Flyers)


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Yusuff Mustapha
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Yusuff Mustapha is a software developer,who uses Python and Web Technologies to create amazing websites
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The week's best photojournalism A giraffe sits with a dog, a woodpecker gets bagged, and more 22 Nov 2019, 21:59 by Jacob Lambert A stray dog stands in a garbage dump near Ahmedabad, India.REUTERS/Amit Dave A Belgian Malinois sits with an orphaned giraffe in South Africa's Limpopo province.AP Photo/Jerome Delay A red-cockaded woodpecker is weighed by a biologist at Fort Bragg, North Carolina.AP Photo/Robert F. Bukaty Swans dive for food in Germany's Lake Constance.AP Photo/Michael Probst Men ride horses in a parade in Mexico City.AP Photo/Rebecca Blackwell Children ride bikes in Ciudad Juarez, Mexico.AP Photo/Cedar Attanasio A man points at a homeless boy during a protest in Maracaibo, Venezuela.AP Photo/Rodrigo Abd A child waits for Pope Francis to conduct the Holy Mass at Bangkok's National Stadium.REUTERS/Jorge Silva A man walks under a bridge in Brussels.AP Photo/Francisco Seco A plane flies past a rainbow near Encinitas, California.REUTERS/Mike Blake People photograph an air show in Dubai.REUTERS/Mahmoud Khaled An audience member reaches for a spilled drink during a Trump rally in Bossier City, Louisiana.REUTERS/Tom Brenner **See last week's best photojournalism**


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Publicly available data from open sources (census.gov, NOAA, data.gov, etc.) are vital resources for students and researchers in a variety of disciplines. Unfortunately, processing these datasets is often tedious and cumbersome. Organizations follow distinctive practices for codifying datasets. Combining data from different sources requires mapping common entities (city, county, etc.) and resolving different types of keys/identifiers. This process is time consuming and can increase the likelihood for methodological errors.
Data Commons attempts to synthesize a single graph from these different data sources. It links references to the same entities (such as cities, counties, organizations, etc.) across different datasets to nodes on the graph, so that users can access data about a particular entity aggregated from different sources without data cleaning or joining. Like the Web, Data Commons is open - any user can contribute datasets or build applications powered by the graph. In the long term, we hope the data contained within Data Commons will be useful to students, researchers, and enthusiasts across different disciplines. Though we've "jump-started" the graph with data from publicly available sources (CDC, US Census, FBI, etc.), we encourage you to join and contribute.


How To Play:
WASD & Space controls the wee little spaceship
ArrowKeys play tetris! Enter will reset the tetris field.
Green cubes will heal your ship
Red cubes will recharge the weapons
Blue cubes will recharge the engines
Log on to the same host (ip):(port) to play against each other!
Hit it!
If there are a lot of players in game, you might want to set up
your own server. Grab stuff from:
here,
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in the game directory
Navigate to localhost:1337 to play directly on the server, or (ip):1337 for remote.
Created for TOJAM2012
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I'm the writer, illustrator & designer of this story book for children, which I completed over a weekend.


| 8:00-8:30 | Registration and Breakfast |
| 8:30-9:00 | NSF Program Managers and Organizers Welcome |
| 9:00-9:40 | Professor Steven Brunton, University of Washington |
| 9:40-10:20 | Professor George Karniadakis, Brown University |
| 10:20-10:40 | Coffee Break |
| 10:40-11:20 | Professor Sharath Girimaji, Texas A&M University |
| 11:20-12:00 | Profesor Weinan E, Princeton University |
| 12:00-13:30 | Lunch |
| 13:30-14:10 | Dr. Mujeeb Malik, NASA Langley Research Center |
| 14:10-14:50 | Professor Karen Willcox, University of Texas at Austin |
| 14:50-15:30 | Coffee Break |
| 15:30-17:00 | Panel Discussion |
| 17:00-18:30 | Poster Session |
| 8:00-8:45 | Breakfast and Registration |
| 8:45-9:00 | Introduction and Overview |
| 9:00-9:40 | Profesor Michael Brenner, Harvard University |
| 9:40-10:20 | Professor Gianluca Iaccarino, Stanford University |
| 10:20-10:40 | Coffee Break |
| 10:40-11:20 | Dr. Kevin Carlberg, Facebook |
| 11:20-12:00 | Profesor Eric Shaqfeh, Stanford University |
| 12:00-13:30 | Lunch |
| 13:30-14:10 | Professor Linau Ren, Tsinghua University |
| 14:10-14:50 | Professor Justin Sirignano, University of Illinois at Urbana-Champaign |
| 14:50-15:30 | Coffee Break |
| 15:30-17:00 | Panel Discussion |
| 17:00 | Adjourn |


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Hey all, looking for feedback on this logo that @hardikv made. Goes along pretty well with the video intro to the show that he put together.
https://www.youtube.com/watch?v=1HQ6cVluTT0&feature=youtu.be
What is the Minnow Mayor Town Hall?
I run a radio show on msp-waves. It’s housed in the Peace, Abundance, and Liberty Discord Channel. It’s a way to allow members of the 16,000 Steemian Discord community to come on air and talk about whatever they would like.  I guess also don’t post random links during muh show (on topic ones are welcome).
What can you do?
Literally, anyone on the platform who isn’t currently banned from PALnet is welcome to attend. You can promote yourself, say hi, introduce a project, read something, perform something. I don’t care. It’s all welcome. It’s kinda my version of the Steem Muppet Show. Everything goes (as long as you’re within community standards).
How to join?
Just hop into Discord and on the left side fo the screen you’ll double click on the radio room and be able to listen in.
If you click on the audience channel you’ll be able to interact by text.
If you hop in the waiting room I’ll bring you on air. While waiting to come on air it’s helpful to listen to the show via mspwaves.com/listen (instead of through Discord).
Special Guests?
Don’t have any planned tonight. So it’s open to whomever. Hopefully some of the musicians will show up and share their talents with us.
Delegation
I don’t really do this anymore. Folks that think they participate in a lot of MSP activities and aren’t currently on msp-active are welcome to ask me in a 1-3 sentence pitch why they should be on there and I’m generally fairly generous with adding folks that are active.
Dice Bitches
We’ll play dice. 25 SBD.
 If I win once we’ll replay. If I win twice I’ll just do a roll off.
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--- layout: post title: 'American Experience: The Donner Party' date: 2011-10-23 09:16:15.000000000 -07:00 type: post published: true status: publish categories: [] tags: [] meta: _edit_last: '1' author: login: admin email<EMAIL_ADDRESS>display_name: admin first_name: Carina C. last_name: Zon ---
I've taken to playing episodes from the archives of American Experience while working out. Today's was "The Donner Party". A story far more complex and sad than legend suggests.


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Smithy Lane House / Fasciato Architects
- Curated by Paula Pintos
- about 17 hours
Houses · Cheshire, United Kingdom
- version="1.0" encoding="UTF-8"? Architects: Fasciato Architects
- AreaArea of this architecture projectArea: 550.0 m2
- version="1.0" encoding="UTF-8"?YearCompletion year of this architecture project Year: 2019
- version="1.0" encoding="UTF-8"?PhotographsPhotographs: French & Tye, CUPA Pizarras
- version="1.0" encoding="UTF-8"?ManufacturersBrands with products used in this architecture project Manufacturers: Adobe, Aerin, AutoDesk, Bulthaup, Hormann, Ibstock, K Rend, Lee Broom, Made, Porcelanosa, Rais, Reynaers Slim, Tom Dixon, Trimble
- Lead Architects Ian Scullion
- Engineering Atkinson Peck
- Consultants Quantity Surveyor Construction Q
- Collaborators HD Builders, Peak Eco
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Text description provided by the architects. The house is based on a cruciform plan with parapet gabled walls defining the end of each wing. The parapet gabled walls and pitched slate roofs create simple, clean forms accentuated by the external material choices of white render and masonry, while traditional architectural details such as exposed rafter ends, stone copings and brick chimneys create a solid, grounded aesthetic. The large expanses of glazing add to the crisp modern appearance and the cruciform layout allows for visual connections between the separate wings of the house as well as to the walled garden and the surrounding grounds.
Internally, the interior spaces are in contrast to the low-level architectural appearance of the exterior. Within the family and formal wings, high pitched ceilings allow extensive light into the spaces, whereas the relatively low ceilings of the bedroom wing provide a more intimate and calm atmosphere. However, the most unexpected element of the design is at the meeting point of the four wings. In the center of the single-story house a large, bespoke glazed lantern forms the ceiling of the entrance hall, flooding the space with light and air.
From this dramatic central space, the four wings of the house separate the accommodation into different uses: family living, formal, bedrooms and services. Although each wing has its own interior design ambiance, the different spaces are connected through a considered palette of materials. Pale tiled floors, dark-framed windows, white walls, and oak joinery provide an understated backdrop. The glazed link with slender circular columns, the large windows of the master bedroom and family room allow connection to the private walled garden from different areas of the house. The high performing building fabric, in conjunction with sustainable technologies such as air source heat pumps and solar PV panels, results in a high standard 5-star EPC rating and SAP Band A rating.
The client's brief was ambiguous, their only stipulation was that the house should be single-story and have level access. Our aim was to design a contemporary take on a traditional house type while steering away from being too trend-focused or fashionable. Our ethos within the practice is to design long-lasting, considered, thoughtful architecture and create internal environments that recognize how people actually use spaces. The house is beyond our client's expectations, providing large, generous, connected spaces that reflect the way they live and also take advantage of the substantial surroundings.


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| DevIL Documentation | Home | Previous | Next |
The iluGetImageInfo function retrieves information about the current image in an easy format.
ILvoid iluGetImageInfo(
ILinfo *Info);
The iluGetImageInfo function retrieves information about the current image in an ILinfo struct. This is useful when you are repeatedly calling ilGetInteger and is more efficient in this case. The ILinfo struct is described below:
typedef struct ILinfo
{
ILU_ILLEGAL_OPERATION - There is currently no image bound. Use ilGenImages and ilBindImage before calling this function. This error is also produced when Info is NULL.
ilGetBoolean, ilGetBooleanv, ilGetInteger, ilGetIntegerv


This presentation is an HTML5 website
Press → key to advance.
rest - n. - peace, ease, or refreshment resulting from the insight that the web works
No matter what vendors tell you - no need to “Light Up the Web” - relax - built on an open architecture using universal identifiers, formats & protocols and evolving open standards - no need to reinvent the wheel and sign-up for single-vendor offerings.


About
At Liquor Park we’re passionate about thoughtful, carefully crafted beverages. By tapping our combined twenty years’ experience in the Chicago industry, we’ve curated a collection of cult-favorite beers, sought-after spirits, and small-batch wines from around the world, including artisan and made in the Midwest products you can’t get just anywhere.
Our shelves are stocked and we’re ready to deliver spot-on pairings and killer recommendations for any palate, budget, or occasion. Come find us in the heart of Wicker Park–Bucktown, just east of the intersection of North, Damen, and Milwaukee Avenues at 1937 West North Avenue.
Email<EMAIL_ADDRESS>Hours and Location
| Mon | 1:00 pm–8:00 pm | |
|---|---|---|
| Tue | 12:00 pm–9:00 pm | |
| Wed | 12:00 pm–9:00 pm | |
| Thu | 12:00 pm–9:00 pm | |
| Fri | 12:00 pm–10:00 pm | |
| Sat | 12:00 pm–10:00 pm | Open |
| Sun | 12:00 pm–8:00 pm |
Events
Cool Wine Tasting
Cool Wine Tasting
Cool Wine Tasting
Wine Club
The Wine Club is the best way to experience the wines that Liquor Park has to offer.
Each month the staff brings you wines that are hand selected, limited release and great finds.  As with any club there are a number of other benefits for becoming a member after you choose between one of the following options:
JV Membership $39.99/month
With this member pass the Liquor Park team brings you two wines that will normally retail for about $50-$60. Most wines we choose have a great story to tell, pair with the season, or are just a great find.
A-Team $89.99/month
This is a unique club. Think California Cult wines, Estate grown grapes that are limited production and limited distribution. Occasionally there maybe a bottle of unique scotch or whiskey instead of wine.
More BENEFITS upon JOINING THE LIQUOR PARK WINE CLUB
In addition to our great monthly wines, you will also receive:
-10% off everything in the shop...
Talk to us in store to sign up!


THE MANDALORIAN - Video Points Out 61 Easter Eggs and References
by Joey PaurBy now, I’m sure most of you have seen The Mandalorian. So, with Episode 2 premiering today, I thought now would be a safe time to share this video from Screen Crush that points out 61 Easter eggs and references from the first episode.
As you’re aware, the episode was loaded with all kinds of stuff. Some of these are harder to spot than others and you may have missed some of them, but this helpful video is here to point them all out to you and explains what they mean and how some might be more significant in upcoming episodes of the series.
Of course, if you haven’t watched the show yet then you might want to skip this.


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If you wish to be informed about what Personal Data we hold about you and if you want it to be removed from our systems, please contact us.
In certain circumstances, you have the following data protection rights:
The right to access, update or delete the information we have on you. Whenever made possible, you can access, update or request deletion of your Personal Data directly within your account settings section. If you are unable to perform these actions yourself, please contact us to assist you.
The right of rectification. You have the right to have your information rectified if that information is inaccurate or incomplete.
The right to object. You have the right to object to our processing of your Personal Data.
The right of restriction. You have the right to request that we restrict the processing of your personal information.
The right to data portability. You have the right to be provided with a copy of the information we have on you in a structured, machine-readable and commonly used format.
The right to withdraw consent. You also have the right to withdraw your consent at any time where That or This relied on your consent to process your personal information.
Please note that we may ask you to verify your identity before responding to such requests.
You have the right to complain to a Data Protection Authority about our collection and use of your Personal Data. For more information, please contact your local data protection authority in the European Economic Area (EEA).
We may employ third party companies and individuals to facilitate our Service ("Service Providers"), provide the Service on our behalf, perform Service-related services or assist us in analysing how our Service is used.
These third parties have access to your Personal Data only to perform these tasks on our behalf and are obligated not to disclose or use it for any other purpose.
Our Service may contain links to other sites that are not operated by us. If you click a third party link, you will be directed to that third party's site. We strongly advise you to review the Privacy Policy of every site you visit.
We have no control over and assume no responsibility for the content, privacy policies or practices of any third party sites or services.
Our Service does not address anyone under the age of 18 ("Children").
We do not knowingly collect personally identifiable information from anyone under the age of 18. If you are a parent or guardian and you are aware that your Child has provided us with Personal Data, please contact us. If we become aware that we have collected Personal Data from children without verification of parental consent, we take steps to remove that information from our servers.
We may update our Privacy Policy from time to time. We will notify you of any changes by posting the new Privacy Policy on this page.
We will let you know via email and/or a prominent notice on our Service, prior to the change becoming effective and update the "effective date" at the top of this Privacy Policy.
You are advised to review this Privacy Policy periodically for any changes. Changes to this Privacy Policy are effective when they are posted on this page.
If you have any questions about this Privacy Policy, please contact us: